This is a tough one. The 5850 is a slightly faster card in single card setup. But Crossfire performance of the 6850 is better as Pezz said. Plus the 6850 has better Tessellation performance which will future proof your setup and the 6850 chip has better power consumption.
The reason for keeping the 5850 is as u stated the hassle of selling the current card you have.
AMD Phenom II X4 960T Zosma @ 4GHz | Thermalright Ultima 90 CPU cooler | GIGBABYTE GA-MA790X-UD4P | Sapphire 6950 unlocked | 6Gb Gskill RAM | 1.5TB total HD | Dell U2412M IPS Monitor | Zalman 750W PSU | LENOVO SL500